We are going to create a following custom block in admin/config page.

Drupal admin/config block - Configure Products

To create a block in admin/config like those 'People, Content Authoring, Media' etc. We need to define two menu items as shown below

function products_menu() {  
    $items = array();  
    $items['admin/config/products'] = array(  
        'title' => 'Configure Products',  
        'description' => 'Allows administrators to configure product items',  
        'weight' => -30,  
        'page callback' => 'drupal_get_form',  
        'page arguments' => array('products_admin_settings_form'),  
        'access arguments' => array('administer products'),  
        'file' => 'products.admin.inc',  
    );

    $items['admin/config/products/manage'] = array(  
        'title' => 'Manage Products',  
        'description' => 'Allows admins to manage products',  
        'page callback' => 'drupal_get_form',  
        'page arguments' => array('products_admin_settings_form'),  
        'access arguments' => array('administer products'),  
        'file' => 'products.admin.inc',  
        'weight' => -10,  
    );

    return $items;  
}

admin/config/products – highlighted above line no. 3

Creates a new block with title Configure Products

admin/config/products/manage – highlighted above line no. 13

This menu item is visible under the Configure Products as clickable item. When this link “Manage Products” is clicked, it invokes the ‘products_admin_settings_form’ page callback which eventually displays a form for products configuration.

If there is any confusions please post them on comment.